First off, my bad to Dobrota—I totally messed up the Standard Deviation formulas earlier. I botched the N-1 part by forgetting to subtract 1, which you can actually see in cells B14 and B35 in the screenshot. This time, I’m sticking to a Microsoft example and that other one Betty Hayes10 shared with us.
Everything's fixed now, and here are the actual formulas:

Betty Hayes10 said:You don't need SUM or POWER or whatever; just grab the test results and use the STDEV function.LINK
Betty Hayes10, what you posted is way off. If you use the STDEV formula, you should be getting 4.47. And if you follow the step-by-step method like I did, the result has to match.
Just a heads up, we square things during the calculation specifically to get rid of those negative signs in the deviations.
I'm sure you get why I went through the whole step-by-step process—just trying to make sure I actually learned how this works. 😉